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Write a Generic Lewis Structure for the Elements in the Oxygen Family (Group 6a).

Chapter 7. Chemic Bonding and Molecular Geometry

seven.3 Lewis Symbols and Structures

Learning Objectives

By the cease of this section, you volition be able to:

  • Write Lewis symbols for neutral atoms and ions
  • Draw Lewis structures depicting the bonding in simple molecules

Thus far in this chapter, we have discussed the various types of bonds that form between atoms and/or ions. In all cases, these bonds involve the sharing or transfer of valence trounce electrons betwixt atoms. In this section, we volition explore the typical method for depicting valence shell electrons and chemical bonds, namely Lewis symbols and Lewis structures.

Lewis Symbols

Nosotros apply Lewis symbols to depict valence electron configurations of atoms and monatomic ions. A Lewis symbol consists of an elemental symbol surrounded by one dot for each of its valence electrons:

A Lewis structure of calcium is shown. A lone pair of electrons are shown to the right of the symbol.

Figure ane shows the Lewis symbols for the elements of the tertiary flow of the periodic table.

A table is shown that has three columns and nine rows. The header row reads
Effigy 1. Lewis symbols illustrating the number of valence electrons for each element in the third period of the periodic tabular array.

Lewis symbols can also be used to illustrate the formation of cations from atoms, as shown here for sodium and calcium:

Two diagrams are shown. The left diagram shows a Lewis dot structure of sodium with one dot, then a right-facing arrow leading to a sodium symbol with a superscripted plus sign, a plus sign, and the letter

As well, they can be used to show the formation of anions from atoms, equally shown hither for chlorine and sulfur:

Two diagrams are shown. The left diagram shows a Lewis dot structure of chlorine with seven dots and the letter

Figure 2 demonstrates the use of Lewis symbols to show the transfer of electrons during the formation of ionic compounds.

A table is shown with four rows. The header row reads
Effigy 2. Cations are formed when atoms lose electrons, represented by fewer Lewis dots, whereas anions are formed past atoms gaining electrons. The full number of electrons does not change.

Lewis Structures

Nosotros also use Lewis symbols to indicate the formation of covalent bonds, which are shown in Lewis structures, drawings that describe the bonding in molecules and polyatomic ions. For instance, when two chlorine atoms form a chlorine molecule, they share one pair of electrons:

A Lewis dot diagram shows a reaction. Two chlorine symbols, each surrounded by seven dots are separated by a plus sign. The dots on the first atom are all black and the dots on the second atom are all read. The phrase,

The Lewis structure indicates that each Cl cantlet has three pairs of electrons that are not used in bonding (chosen lone pairs) and ane shared pair of electrons (written between the atoms). A dash (or line) is sometimes used to indicate a shared pair of electrons:

Two Lewis structures are shown. The left-hand structure shows two H atoms connected by a single bond. The right-hand structure shows two C l atoms connected by a single bond and each surrounded by six dots.

A unmarried shared pair of electrons is called a single bond. Each Cl atom interacts with viii valence electrons: the six in the lone pairs and the two in the single bond.

The Octet Dominion

The other halogen molecules (F2, Br2, I2, and Attwo) course bonds like those in the chlorine molecule: 1 single bond between atoms and three lonely pairs of electrons per atom. This allows each halogen atom to take a noble gas electron configuration. The tendency of main group atoms to grade enough bonds to obtain eight valence electrons is known as the octet rule.

The number of bonds that an atom tin form can frequently be predicted from the number of electrons needed to reach an octet (viii valence electrons); this is especially true of the nonmetals of the second flow of the periodic table (C, N, O, and F). For example, each atom of a group fourteen element has four electrons in its outermost shell and therefore requires four more than electrons to reach an octet. These four electrons tin be gained past forming four covalent bonds, equally illustrated here for carbon in CClfour (carbon tetrachloride) and silicon in SiHiv (silane). Because hydrogen only needs two electrons to fill up its valence beat out, it is an exception to the octet rule. The transition elements and inner transition elements also do not follow the octet rule:

Two sets of Lewis dot structures are shown. The left structures depict five C l symbols in a cross shape with eight dots around each, the word

Grouping 15 elements such every bit nitrogen have five valence electrons in the diminutive Lewis symbol: ane lone pair and three unpaired electrons. To obtain an octet, these atoms form three covalent bonds, as in NHthree (ammonia). Oxygen and other atoms in grouping xvi obtain an octet by forming two covalent bonds:

Three Lewis structures labeled,

Double and Triple Bonds

As previously mentioned, when a pair of atoms shares i pair of electrons, we call this a single bond. However, a pair of atoms may need to share more than than 1 pair of electrons in order to accomplish the requisite octet. A double bond forms when ii pairs of electrons are shared between a pair of atoms, as between the carbon and oxygen atoms in CHtwoO (formaldehyde) and betwixt the two carbon atoms in C2Hiv (ethylene):

Two pairs of Lewis structures are shown. The left pair of structures shows a carbon atom forming single bonds to two hydrogen atoms. There are four electrons between the C atom and an O atom. The O atom also has two pairs of dots. The word

A triple bail forms when three electron pairs are shared by a pair of atoms, as in carbon monoxide (CO) and the cyanide ion (CN):

Two pairs of Lewis structures are shown and connected by a right-facing arrow. The left pair of structures show a C atom and an O atom with six dots in between them and a lone pair on each. The word

Writing Lewis Structures with the Octet Rule

For very unproblematic molecules and molecular ions, we tin can write the Lewis structures past merely pairing upwards the unpaired electrons on the elective atoms. Meet these examples:

Three reactions are shown with Lewis dot diagrams. The first shows a hydrogen with one red dot, a plus sign and a bromine with seven dots, one of which is red, connected by a right-facing arrow to a hydrogen and bromine with a pair of red dots in between them. There are also three lone pairs on the bromine. The second reaction shows a hydrogen with a coefficient of two and one red dot, a plus sign, and a sulfur atom with six dots, two of which are red, connected by a right facing arrow to two hydrogen atoms and one sulfur atom. There are two red dots in between the two hydrogen atoms and the sulfur atom. Both pairs of these dots are red. The sulfur atom also has two lone pairs of dots. The third reaction shows two nitrogen atoms each with five dots, three of which are red, separated by a plus sign, and connected by a right-facing arrow to two nitrogen atoms with six red electron dots in between one another. Each nitrogen atom also has one lone pair of electrons.

For more complicated molecules and molecular ions, it is helpful to follow the pace-by-step procedure outlined here:

  1. Determine the total number of valence (outer shell) electrons. For cations, subtract i electron for each positive charge. For anions, add together one electron for each negative charge.
  2. Draw a skeleton structure of the molecule or ion, arranging the atoms effectually a cardinal atom. (Mostly, the least electronegative chemical element should exist placed in the center.) Connect each atom to the central atom with a single bond (one electron pair).
  3. Distribute the remaining electrons as lone pairs on the terminal atoms (except hydrogen), completing an octet effectually each cantlet.
  4. Place all remaining electrons on the central atom.
  5. Rearrange the electrons of the outer atoms to make multiple bonds with the central atom in order to obtain octets wherever possible.

Let us determine the Lewis structures of SiHfour, CHOtwo−, NO+, and OF2 as examples in following this procedure:

  1. Determine the full number of valence (outer beat out) electrons in the molecule or ion.
    • For a molecule, we add together the number of valence electrons on each cantlet in the molecule:

      [latex]\begin{assortment}{r r l} \text{SiH}_4 & & \\[1em] & \text{Si: iv valence electrons/atom} \times 1 \;\text{cantlet} & = iv \\[1em] \rule[-0.5ex]{21em}{0.1ex}\hspace{-21em} + & \text{H: 1 valence electron/atom} \times 4 \;\text{atoms} & = 4 \\[1em] & & = 8 \;\text{valence electrons} \stop{array}[/latex]

    • For a negative ion, such as CHOii , we add together the number of valence electrons on the atoms to the number of negative charges on the ion (one electron is gained for each single negative accuse):

      [latex]\begin{array}{r r l} {\text{CHO}_2}^{-} & & \\[1em] & \text{C: 4 valence electrons/atom} \times 1 \;\text{cantlet} & = 4 \\[1em] & \text{H: one valence electron/atom} \times i \;\text{atom} & = 1 \\[1em] & \text{O: 6 valence electrons/atom} \times two \;\text{atoms} & = 12 \\[1em] \rule[-0.5ex]{21.5em}{0.1ex}\hspace{-21.5em} + & 1\;\text{additional electron} & = i \\[1em] & & = eighteen \;\text{valence electrons} \end{array}[/latex]

    • For a positive ion, such as NO+, nosotros add the number of valence electrons on the atoms in the ion and and so subtract the number of positive charges on the ion (ane electron is lost for each single positive accuse) from the total number of valence electrons:

      [latex]\begin{array}{r r 50} \text{NO}^{+} & & \\[1em] & \text{Due north: 5 valence electrons/cantlet} \times one \;\text{atom} & = 5 \\[1em] & \text{O: vi valence electrons/atom} \times one \;\text{atom} & = 6 \\[1em] \dominion[-0.5ex]{21em}{0.1ex}\hspace{-21em} + & -1 \;\text{electron (positive accuse)} & = -1 \\[1em] & & = 10 \;\text{valence electrons} \end{assortment}[/latex]

    • Since OF2 is a neutral molecule, we simply add the number of valence electrons:

      [latex]\begin{array}{r r 50} \text{OF}_{2} & & \\[1em] & \text{O: 6 valence electrons/atom} \times 1 \;\text{atom} & = half dozen \\[1em] \rule[-0.5ex]{21em}{0.1ex}\hspace{-21em} + & \text{F: 7 valence electrons/atom} \times 2 \;\text{atoms} & = xiv \\[1em] & & = 20 \;\text{valence electrons} \finish{array}[/latex]

  2. Draw a skeleton construction of the molecule or ion, arranging the atoms effectually a central cantlet and connecting each cantlet to the cardinal atom with a unmarried (one electron pair) bail. (Notation that nosotros denote ions with brackets around the structure, indicating the charge outside the brackets:)Four Lewis diagrams are shown. The first shows one silicon single boned to four hydrogen atoms. The second shows a carbon which forms a single bond with an oxygen and a hydrogen and a double bond with a second oxygen. This structure is surrounded by brackets and has a superscripted negative sign near the upper right corner. The third structure shows a nitrogen single bonded to an oxygen and surrounded by brackets with a superscripted plus sign in the upper right corner. The last structure shows two fluorine atoms single bonded to a central oxygen.When several arrangements of atoms are possible, as for CHOii , we must use experimental prove to choose the right i. In general, the less electronegative elements are more than probable to be primal atoms. In CHO2 , the less electronegative carbon atom occupies the central position with the oxygen and hydrogen atoms surrounding it. Other examples include P in POCl3, S in And so2, and Cl in ClO4 . An exception is that hydrogen is almost never a fundamental atom. As the near electronegative element, fluorine besides cannot exist a central cantlet.
  3. Distribute the remaining electrons as lone pairs on the terminal atoms (except hydrogen) to complete their valence shells with an octet of electrons.
    • In that location are no remaining electrons on SiH4, then information technology is unchanged:Four Lewis structures are shown. The first shows one silicon single boned to four hydrogen atoms. The second shows a carbon single bonded to two oxygen atoms that each have three lone pairs and single bonded to a hydrogen. This structure is surrounded by brackets and has a superscripted negative sign near the upper right corner. The third structure shows a nitrogen single bonded to an oxygen, each with three lone pairs of electrons. This structure is surrounded by brackets with a superscripted plus sign in the upper right corner. The last structure shows two fluorine atoms, each with three lone pairs of electrons, single bonded to a central oxygen.
  4. Place all remaining electrons on the primal atom.
    • For SiH4, CHOii , and NO+, in that location are no remaining electrons; we already placed all of the electrons determined in Stride 1.
    • For OFii, we had 16 electrons remaining in Step iii, and we placed 12, leaving 4 to exist placed on the key atom:A Lewis structure shows two fluorine atoms, each with three lone pairs of electrons, single bonded to a central oxygen which has two lone pairs of electrons.
  5. Rearrange the electrons of the outer atoms to brand multiple bonds with the fundamental atom in order to obtain octets wherever possible.

Example i

Writing Lewis Structures
NASA's Cassini-Huygens mission detected a large deject of toxic hydrogen cyanide (HCN) on Titan, 1 of Saturn's moons. Titan as well contains ethane (H3CCH3), acetylene (HCCH), and ammonia (NH3). What are the Lewis structures of these molecules?

Solution

  1. Calculate the number of valence electrons.HCN: (i × 1) + (4 × i) + (5 × ane) = 10HiiiCCH3: (ane × 3) + (2 × 4) + (i × iii) = 14HCCH: (1 × 1) + (2 × four) + (ane × 1) = 10NH3: (5 × i) + (3 × 1) = viii
  2. Draw a skeleton and connect the atoms with single bonds. Call up that H is never a fundamental atom:Four Lewis structures are shown. The first structure shows a carbon atom single bonded to a hydrogen atom and a nitrogen atom. The second structure shows two carbon atoms single bonded to one another. Each is single bonded to three hydrogen atoms. The third structure shows two carbon atoms single bonded to one another and each single bonded to one hydrogen atom. The fourth structure shows a nitrogen atom single bonded to three hydrogen atoms.
  3. Where needed, distribute electrons to the concluding atoms: Four Lewis structures are shown. The first structure shows a carbon atom single bonded to a hydrogen atom and a nitrogen atom, which has three lone pairs of electrons. The second structure shows two carbon atoms single bonded to one another. Each is single bonded to three hydrogen atoms. The third structure shows two carbon atoms single bonded to one another and each single bonded to one hydrogen atom. The fourth structure shows a nitrogen atom single bonded to three hydrogen atoms.HCN: 6 electrons placed on NH3CCH3: no electrons remainHCCH: no concluding atoms capable of accepting electrons

    NHiii: no terminal atoms capable of accepting electrons

  4. Where needed, identify remaining electrons on the central atom: Four Lewis structures are shown. The first structure shows a carbon atom single bonded to a hydrogen atom and a nitrogen atom, which has three lone pairs of electrons. The second structure shows two carbon atoms single bonded to one another. Each is single bonded to three hydrogen atoms. The third structure shows two carbon atoms, each with a lone pair of electrons, single bonded to one another and each single bonded to one hydrogen atom. The fourth structure shows a nitrogen atom with a lone pair of electrons single bonded to three hydrogen atoms.HCN: no electrons remainHthreeCCH3: no electrons remainHCCH: four electrons placed on carbon

    NHthree: two electrons placed on nitrogen

  5. Where needed, rearrange electrons to course multiple bonds in social club to obtain an octet on each atom:HCN: form 2 more C–N bondsH3CCH3: all atoms accept the correct number of electronsHCCH: form a triple bond between the two carbon atomsNH3: all atoms have the correct number of electrons

    Four Lewis structures are shown. The first structure shows a carbon atom single bonded to a hydrogen atom and a nitrogen atom, which has three lone pairs of electrons. Two curved arrows point from the nitrogen to the carbon. Below this structure is the word

Check Your Learning
Both carbon monoxide, CO, and carbon dioxide, CO2, are products of the combustion of fossil fuels. Both of these gases as well cause problems: CO is toxic and COtwo has been implicated in global climate alter. What are the Lewis structures of these ii molecules?

Answer:

Two Lewis structures are shown. The left shows a carbon triple bonded to an oxygen, each with a lone electron pair. The right structure shows a carbon double bonded to an oxygen on each side. Each oxygen has two lone pairs of electrons.

Fullerene Chemistry

Carbon soot has been known to homo since prehistoric times, but information technology was not until adequately recently that the molecular structure of the main component of soot was discovered. In 1996, the Nobel Prize in Chemical science was awarded to Richard Smalley (Figure 3), Robert Gyre, and Harold Kroto for their work in discovering a new form of carbon, the Cthreescore buckminsterfullerene molecule (Figure 1 in Chapter 7 Introduction). An entire course of compounds, including spheres and tubes of various shapes, were discovered based on Csixty. This type of molecule, called a fullerene, shows promise in a diversity of applications. Considering of their size and shape, fullerenes tin encapsulate other molecules, so they have shown potential in various applications from hydrogen storage to targeted drug delivery systems. They also possess unique electronic and optical properties that have been put to good use in solar powered devices and chemical sensors.

A photo of Richard Smalley is shown.
Figure 3. Richard Smalley (1943–2005), a professor of physics, chemistry, and astronomy at Rice University, was one of the leading advocates for fullerene chemistry. Upon his death in 2005, the US Senate honored him as the "Father of Nanotechnology." (credit: U.s.a. Section of Energy)

Exceptions to the Octet Rule

Many covalent molecules have central atoms that practice not have eight electrons in their Lewis structures. These molecules fall into three categories:

  • Odd-electron molecules have an odd number of valence electrons, and therefore take an unpaired electron.
  • Electron-deficient molecules have a fundamental atom that has fewer electrons than needed for a noble gas configuration.
  • Hypervalent molecules have a central atom that has more electrons than needed for a noble gas configuration.

Odd-electron Molecules

We phone call molecules that incorporate an odd number of electrons free radicals. Nitric oxide, NO, is an case of an odd-electron molecule; it is produced in internal combustion engines when oxygen and nitrogen react at high temperatures.

To draw the Lewis construction for an odd-electron molecule similar NO, we follow the aforementioned five steps we would for other molecules, just with a few minor changes:

  1. Determine the full number of valence (outer crush) electrons. The sum of the valence electrons is 5 (from N) + vi (from O) = eleven. The odd number immediately tells us that nosotros have a free radical, and then we know that not every atom tin can take eight electrons in its valence shell.
  2. Draw a skeleton structure of the molecule. Nosotros tin easily draw a skeleton with an North–O single bail:N–O
  3. Distribute the remaining electrons as solitary pairs on the concluding atoms. In this case, there is no central atom, so nosotros distribute the electrons effectually both atoms. We give viii electrons to the more electronegative atom in these situations; thus oxygen has the filled valence beat:
    A Lewis structure shows a nitrogen atom, with one lone pair and one lone electron single bonded to an oxygen atom with three lone pairs of electrons.
  4. Place all remaining electrons on the fundamental atom. Since there are no remaining electrons, this step does non apply.
  5. Rearrange the electrons to make multiple bonds with the central atom in order to obtain octets wherever possible. Nosotros know that an odd-electron molecule cannot accept an octet for every cantlet, but nosotros desire to get each atom every bit close to an octet every bit possible. In this case, nitrogen has only five electrons around information technology. To move closer to an octet for nitrogen, we take ane of the lone pairs from oxygen and utilise it to grade a NO double bond. (We cannot take another lonely pair of electrons on oxygen and form a triple bond because nitrogen would then have 9 electrons:)
    A Lewis structure shows a nitrogen atom, with one lone pair and one lone electron double bonded to an oxygen atom with two lone pairs of electrons.

Electron-deficient Molecules

Nosotros will also meet a few molecules that contain central atoms that do not have a filled valence shell. By and large, these are molecules with central atoms from groups ii and 12, outer atoms that are hydrogen, or other atoms that practice not form multiple bonds. For case, in the Lewis structures of glucinium dihydride, BeH2, and boron trifluoride, BF3, the beryllium and boron atoms each have simply 4 and six electrons, respectively. It is possible to draw a structure with a double bond between a boron atom and a fluorine atom in BF3, satisfying the octet rule, but experimental evidence indicates the bail lengths are closer to that expected for B–F unmarried bonds. This suggests the best Lewis structure has three B–F single bonds and an electron deficient boron. The reactivity of the compound is also consistent with an electron deficient boron. Even so, the B–F bonds are slightly shorter than what is really expected for B–F unmarried bonds, indicating that some double bond graphic symbol is found in the bodily molecule.

Two Lewis structures are shown. The left shows a beryllium atom single bonded to two hydrogen atoms. The right shows a boron atom single bonded to three fluorine atoms, each with three lone pairs of electrons.

An atom like the boron atom in BF3, which does non have eight electrons, is very reactive. It readily combines with a molecule containing an atom with a lonely pair of electrons. For instance, NH3 reacts with BFiii because the lone pair on nitrogen tin be shared with the boron atom:

A reaction is shown with three Lewis diagrams. The left diagram shows a boron atom single bonded to three fluorine atoms, each with three lone pairs of electrons. There is a plus sign. The next structure shows a nitrogen atom with one lone pair of electrons single bonded to three hydrogen atoms. A right-facing arrow leads to the final Lewis structure that shows a boron atom single bonded to a nitrogen atom and single bonded to three fluorine atoms, each with three lone pairs of electrons. The nitrogen atom is also single bonded to three hydrogen atoms. The bond between the boron atom and the nitrogen atom is colored red.

Hypervalent Molecules

Elements in the second period of the periodic table (n = ii) tin arrange only eight electrons in their valence shell orbitals because they have only four valence orbitals (i 2s and three 2p orbitals). Elements in the third and higher periods (n ≥ 3) have more than four valence orbitals and can share more four pairs of electrons with other atoms because they have empty d orbitals in the aforementioned shell. Molecules formed from these elements are sometimes called hypervalent molecules. Figure iv shows the Lewis structures for two hypervalent molecules, PCl5 and SF6.

Two Lewis structures are shown. The left shows a phosphorus atom single bonded to five chlorine atoms, each with three lone pairs of electrons. The right shows a sulfur atom single bonded to six fluorine atoms, each with three lone pairs of electrons.
Figure 4. In PCl5, the fundamental atom phosphorus shares 5 pairs of electrons. In SFhalf-dozen, sulfur shares six pairs of electrons.

In some hypervalent molecules, such as IF5 and XeF4, some of the electrons in the outer shell of the central atom are lone pairs:

Two Lewis structures are shown. The left shows an iodine atom with one lone pair single bonded to five fluorine atoms, each with three lone pairs of electrons. The right diagram shows a xenon atom with two lone pairs of electrons single bonded to four fluorine atoms, each with three lone pairs of electrons.

When we write the Lewis structures for these molecules, we find that nosotros take electrons left over after filling the valence shells of the outer atoms with eight electrons. These additional electrons must exist assigned to the fundamental atom.

Example 2

Writing Lewis Structures: Octet Rule Violations
Xenon is a noble gas, just it forms a number of stable compounds. We examined XeF4 earlier. What are the Lewis structures of XeFii and XeF6?

Solution
We can draw the Lewis structure of any covalent molecule by following the six steps discussed earlier. In this case, we tin can condense the concluding few steps, since not all of them utilise.

  1. Calculate the number of valence electrons: XeF2: 8 + (two × 7) = 22XeF6: 8 + (6 × 7) = fifty
  2. Describe a skeleton joining the atoms past single bonds. Xenon will be the central atom because fluorine cannot be a cardinal atom:
    Two Lewis diagrams are shown. The left depicts a xenon atom single bonded to two fluorine atoms. The right shows a xenon atom single bonded to six fluorine atoms.
  3. Distribute the remaining electrons.XeF2: We place three lone pairs of electrons effectually each F atom, accounting for 12 electrons and giving each F cantlet 8 electrons. Thus, half dozen electrons (three solitary pairs) remain. These solitary pairs must be placed on the Xe cantlet. This is adequate because Xe atoms have empty valence beat d orbitals and can accommodate more than eight electrons. The Lewis structure of XeF2 shows two bonding pairs and iii lone pairs of electrons effectually the Xe cantlet:
    A Lewis diagram shows a xenon atom with three lone pairs of electrons single bonded to two fluorine atoms, each with three lone pairs of electrons.XeFhalf dozen: We place three alone pairs of electrons around each F cantlet, bookkeeping for 36 electrons. Two electrons remain, and this lone pair is placed on the Xe atom:This structure shows a xenon atom single bonded to six fluorine atoms. Each fluorine atom has three lone pairs of electrons.

Cheque Your Learning
The halogens form a class of compounds called the interhalogens, in which halogen atoms covalently bond to each other. Write the Lewis structures for the interhalogens BrCl3 and ICl4 .

Respond:

Two Lewis structures are shown. The left depicts a bromine atom with two lone pairs of electrons single bonded to three chlorine atoms, each with three lone pairs of electrons. The right shows an iodine atom, with two lone pairs of electrons, single boned to four chlorine atoms, each with three lone pairs of electrons. This structure is surrounded by brackets and has a superscripted negative sign.

Key Concepts and Summary

Valence electronic structures tin can exist visualized by drawing Lewis symbols (for atoms and monatomic ions) and Lewis structures (for molecules and polyatomic ions). Lone pairs, unpaired electrons, and single, double, or triple bonds are used to indicate where the valence electrons are located around each atom in a Lewis construction. Most structures—peculiarly those containing second row elements—obey the octet rule, in which every atom (except H) is surrounded by eight electrons. Exceptions to the octet rule occur for odd-electron molecules (gratuitous radicals), electron-deficient molecules, and hypervalent molecules.

Chemistry Cease of Chapter Exercises

  1. Write the Lewis symbols for each of the post-obit ions:

    (a) Asthree–

    (b) I

    (c) Be2+

    (d) Oii–

    (due east) Ga3+

    (f) Li+

    (g) N3–

  2. Many monatomic ions are found in seawater, including the ions formed from the post-obit list of elements. Write the Lewis symbols for the monatomic ions formed from the following elements:

    (a) Cl

    (b) Na

    (c) Mg

    (d) Ca

    (eastward) K

    (f) Br

    (one thousand) Sr

    (h) F

  3. Write the Lewis symbols of the ions in each of the following ionic compounds and the Lewis symbols of the atom from which they are formed:

    (a) MgS

    (b) Al2O3

    (c) GaCl3

    (d) 10002O

    (e) LiiiiN

    (f) KF

  4. In the Lewis structures listed hither, M and X represent various elements in the third menstruum of the periodic tabular array. Write the formula of each compound using the chemical symbols of each element:

    (a)

    Two Lewis structures are shown side-by-side, each surrounded by brackets. The left structure shows the symbol M with a superscripted two positive sign. The right shows the symbol X surrounded by four lone pairs of electrons with a superscripted two negative sign outside of the brackets.

    (b)

    Two Lewis structures are shown side-by-side, each surrounded by brackets. The left structure shows the symbol M with a superscripted three positive sign. The right structure shows the symbol X surrounded by four lone pairs of electrons with a superscripted negative sign and a subscripted three both outside of the brackets.

    (c)

    Two Lewis structures are shown side-by-side, each surrounded by brackets. The left structure shows the symbol M with a superscripted positive sign and a subscripted two outside of the brackets. The right structure shows the symbol X surrounded by four lone pairs of electrons with a superscripted two negative sign outside of the brackets.

    (d)

    Two Lewis structures are shown side-by-side, each surrounded by brackets. The left structure shows the symbol M with a superscripted three positive sign and a subscripted two outside of the brackets. The right structure shows the symbol X surrounded by four lone pairs of electrons with a superscripted two negative sign and subscripted three both outside of the brackets.

  5. Write the Lewis structure for the diatomic molecule P2, an unstable form of phosphorus found in high-temperature phosphorus vapor.
  6. Write Lewis structures for the following:

    (a) H2

    (b) HBr

    (c) PCl3

    (d) SFtwo

    (e) H2CCH2

    (f) HNNH

    (chiliad) H2CNH

    (h) NO

    (i) Ntwo

    (j) CO

    (m) CN

  7. Write Lewis structures for the post-obit:

    (a) Otwo

    (b) HiiCO

    (c) AsFiii

    (d) ClNO

    (due east) SiClfour

    (f) H3O+

    (g) NHfour +

    (h) BFfour

    (i) HCCH

    (j) ClCN

    (k) C2 two+

  8. Write Lewis structures for the following:

    (a) ClF3

    (b) PCl5

    (c) BFiii

    (d) PF6

  9. Write Lewis structures for the following:

    (a) SeFhalf dozen

    (b) XeF4

    (c) SeClthree +

    (d) Cl2BBCl2 (contains a B–B bond)

  10. Write Lewis structures for:

    (a) PO4 3−

    (b) IClfour

    (c) SO3 2−

    (d) HONO

  11. Correct the following statement: "The bonds in solid PbCltwo are ionic; the bond in a HCl molecule is covalent. Thus, all of the valence electrons in PbCl2 are located on the Cl ions, and all of the valence electrons in a HCl molecule are shared between the H and Cl atoms."
  12. Write Lewis structures for the following molecules or ions:

    (a) SbH3

    (b) XeF2

    (c) Se8 (a cyclic molecule with a ring of eight Se atoms)

  13. Methanol, H3COH, is used as the fuel in some race cars. Ethanol, C2H5OH, is used extensively as motor fuel in Brazil. Both methanol and ethanol produce CO2 and H2O when they fire. Write the chemical equations for these combustion reactions using Lewis structures instead of chemical formulas.
  14. Many planets in our solar system comprise organic chemicals including methyl hydride (CH4) and traces of ethylene (C2H4), ethane (C2H6), propyne (HiiiCCCH), and diacetylene (HCCCCH). Write the Lewis structures for each of these molecules.
  15. Carbon tetrachloride was formerly used in fire extinguishers for electrical fires. It is no longer used for this purpose because of the germination of the toxic gas phosgene, Cl2CO. Write the Lewis structures for carbon tetrachloride and phosgene.
  16. Identify the atoms that correspond to each of the post-obit electron configurations. Then, write the Lewis symbol for the common ion formed from each cantlet:

    (a) 1s 2iidue south 2twop 5

    (b) 1s ii2s 22p 63s 2

    (c) is 2iisouthward 22p 63s 23p 64south 23d 10

    (d) 1s 22southward 22p 63s 2threep half dozenivs 23d 10ivp 4

    (due east) 1south ii2due south ii2p 63south iiiiip 64south twothreed 10ivp 1

  17. The system of atoms in several biologically of import molecules is given hither. Consummate the Lewis structures of these molecules by adding multiple bonds and lonely pairs. Do not add any more atoms.

    (a) the amino acid serine:

    A Lewis structure is shown. A nitrogen atom is single bonded to two hydrogen atoms and a carbon atom. The carbon atom is single bonded to a hydrogen atom and two other carbon atoms. One of these carbon atoms is single bonded to two hydrogen atoms and an oxygen atom. The oxygen atom is bonded to a hydrogen atom. The other carbon atom is single bonded to two oxygen atoms, one of which is bonded to a hydrogen atom.

    (b) urea:

    A Lewis structure is shown. A nitrogen atom is single bonded to two hydrogen atoms and a carbon atom. The carbon atom is single bonded to an oxygen atom and another nitrogen atom. That nitrogen atom is then single bonded to two hydrogen atoms.

    (c) pyruvic acrid:

    A Lewis structure is shown. A carbon atom is single bonded to three hydrogen atoms and another carbon atom. The second carbon atom is single bonded to an oxygen atom and a third carbon atom. This carbon is then single bonded to two oxygen atoms, one of which is single bonded to a hydrogen atom.

    (d) uracil:

    A Lewis hexagonal ring structure is shown. From the top of the ring (moving clockwise), three carbon atoms, one nitrogen atom, a carbon atom, and a nitrogen atom are single bonded to each another. The top carbon atom is single bonded to an oxygen atom. The second and third carbons and the nitrogen atom are each single bonded to a hydrogen atom. The next carbon atom is single bonded to an oxygen atom, and the last nitrogen atom is single bonded to a hydrogen atom.

    (eastward) carbonic acrid:

    A Lewis structure is shown. A carbon atom is single bonded to three oxygen atoms. Two of those oxygen atoms are each single bonded to a hydrogen atom.

  18. A compound with a molar mass of near 28 g/mol contains 85.7% carbon and fourteen.three% hydrogen by mass. Write the Lewis structure for a molecule of the chemical compound.
  19. A compound with a molar mass of about 42 g/mol contains 85.7% carbon and 14.3% hydrogen past mass. Write the Lewis structure for a molecule of the compound.
  20. Two arrangements of atoms are possible for a compound with a tooth mass of virtually 45 thou/mol that contains 52.2% C, xiii.1% H, and 34.7% O by mass. Write the Lewis structures for the two molecules.
  21. How are unmarried, double, and triple bonds similar? How exercise they differ?

Glossary

double bond
covalent bond in which 2 pairs of electrons are shared between ii atoms
gratis radical
molecule that contains an odd number of electrons
hypervalent molecule
molecule containing at least one main grouping element that has more than eight electrons in its valence shell
Lewis structure
diagram showing solitary pairs and bonding pairs of electrons in a molecule or an ion
Lewis symbol
symbol for an element or monatomic ion that uses a dot to correspond each valence electron in the element or ion
lone pair
two (a pair of) valence electrons that are not used to form a covalent bail
octet rule
guideline that states principal grouping atoms will form structures in which eight valence electrons interact with each nucleus, counting bonding electrons as interacting with both atoms continued by the bond
unmarried bond
bail in which a single pair of electrons is shared between two atoms
triple bond
bond in which three pairs of electrons are shared between ii atoms

Solutions

Answers to Chemistry End of Chapter Exercises

1. (a) viii electrons:
A Lewis dot diagram shows the symbol for arsenic, A s, surrounded by eight dots and a superscripted three negative sign.;

(b) eight electrons:

A Lewis dot diagram shows the symbol for iodine, I, surrounded by eight dots and a superscripted negative sign.;

(c) no electrons

Be2+;

(d) eight electrons:

A Lewis dot diagram shows the symbol for oxygen, O, surrounded by eight dots and a superscripted two negative sign.;

(due east) no electrons

Ga3+;

(f) no electrons

Li+;

(g) viii electrons:

A Lewis dot diagram shows the symbol for nitrogen, N, surrounded by eight dots and a superscripted three negative sign.

3. (a)

Two Lewis structures are shown. The left shows the symbol M g with a superscripted two positive sign while the right shows the symbol S surrounded by eight dots and a superscripted two negative sign.;

(b)

Two Lewis structures are shown. The left shows the symbol A l with a superscripted three positive sign while the right shows the symbol O surrounded by eight dots and a superscripted two negative sign.;

(c)

Two Lewis structures are shown. The left shows the symbol G a with a superscripted three positive sign while the right shows the symbol C l surrounded by eight dots and a superscripted negative sign.;

(d)

Two Lewis structures are shown. The left shows the symbol K with a superscripted positive sign while the right shows the symbol O surrounded by eight dots and a superscripted two negative sign.>;

(due east)

Two Lewis structures are shown. The left shows the symbol L i with a superscripted positive sign while the right shows the symbol N surrounded by eight dots and a superscripted three negative sign.;

(f)

Two Lewis structures are shown. The left shows the symbol K with a superscripted positive sign while the right shows the symbol F surrounded by eight dots and a superscripted negative sign.

5.
A Lewis diagram shows two phosphorus atoms triple bonded together each with one lone electron pair.

7. (a)
A Lewis structure shows two oxygen atoms double bonded together, and each has two lone pairs of electrons.

In this case, the Lewis structure is inadequate to depict the fact that experimental studies have shown two unpaired electrons in each oxygen molecule.

(b)

A Lewis structure shows a carbon atom that is single bonded to two hydrogen atoms and double bonded to an oxygen atom. The oxygen atom has two lone pairs of electrons.;

(c)

A Lewis structure shows an arsenic atom single bonded to three fluorine atoms. Each fluorine atom has a lone pair of electrons.;

(d)

A Lewis structure shows a nitrogen atom with a lone pair of electrons single bonded to a chlorine atom that has three lone pairs of electrons. The nitrogen is also double bonded to an oxygen which has two lone pairs of electrons. ;

(east)

A Lewis structure shows a silicon atom that is single bonded to four chlorine atoms. Each chlorine atom has three lone pairs of electrons.;

(f)

A Lewis structure shows an oxygen atom with a lone pair of electrons single bonded to three hydrogen atoms. The structure is surrounded by brackets with a superscripted positive sign.;

(g)

A Lewis structure shows a nitrogen atom single bonded to four hydrogen atoms. The structure is surrounded by brackets with a superscripted positive sign.;

(h)

A Lewis structure shows a boron atom single bonded to four fluorine atoms. Each fluorine atom has three lone pairs of electrons. The structure is surrounded by brackets with a superscripted negative sign.;

(i)

A Lewis structure shows two carbon atoms that are triple bonded together. Each carbon is also single bonded to a hydrogen atom.;

(j)

A Lewis structure shows a carbon atom that is triple bonded to a nitrogen atom that has one lone pair of electrons. The carbon is also single bonded to a chlorine atom that has three lone pairs of electrons.;

(thousand)

A Lewis structure shows two carbon atoms joined with a triple bond. A superscripted 2 positive sign lies to the right of the second carbon.

9. (a) SeF6:
A Lewis structure shows a selenium atom single bonded to six fluorine atoms, each with three lone pairs of electrons.;

(b) XeF4:

A Lewis structure shows a xenon atom with two lone pairs of electrons. It is single bonded to four fluorine atoms each with three lone pairs of electrons.;

(c) SeCl3 +:

A Lewis structure shows a selenium atom with one lone pair of electrons single bonded to three chlorine atoms each with three lone pairs of electrons. The whole structure is surrounded by brackets.;

(d) CltwoBBCltwo:

A Lewis structure shows two boron atoms that are single bonded together. Each is also single bonded to two chlorine atoms that both have three lone pairs of electrons.

11. 2 valence electrons per Pb atom are transferred to Cl atoms; the resulting Pb2+ ion has a 6southward 2 valence crush configuration. Two of the valence electrons in the HCl molecule are shared, and the other six are located on the Cl atom equally solitary pairs of electrons.

thirteen.
Two reactions are shown using Lewis structures. The top reaction shows a carbon atom, single bonded to three hydrogen atoms and single bonded to an oxygen atom with two lone pairs of electrons. The oxygen atom is also bonded to a hydrogen atom. This is followed by a plus sign and the number one point five, followed by two oxygen atoms bonded together with a double bond and each with two lone pairs of electrons. A right-facing arrow leads to a carbon atom that is double bonded to two oxygen atoms, each of which has two lone pairs of electrons. This structure is followed by a plus sign, a number two, and a structure made up of an oxygen with two lone pairs of electrons single bonded to two hydrogen atoms. The bottom reaction shows a carbon atom, single bonded to three hydrogen atoms and single bonded to another carbon atom. The second carbon atom is single bonded to two hydrogen atoms and one oxygen atom with two lone pairs of electrons. The oxygen atom is also bonded to a hydrogen atom. This is followed by a plus sign and the number three, followed by two oxygen atoms bonded together with a double bond. Each oxygen atom has two lone pairs of electrons. A right-facing arrow leads to a number two and a carbon atom that is double bonded to two oxygen atoms, each of which has two lone pairs of electrons. This structure is followed by a plus sign, a number three, and a structure made up of an oxygen with two lone pairs of electrons single bonded to two hydrogen atoms.

15.
Two Lewis structures are shown. The left depicts a carbon atom single bonded to four chlorine atoms, each with three lone pairs of electrons. The right shows a carbon atom double bonded to an oxygen atom that has two lone pairs of electrons. The carbon atom is also single bonded to two chlorine atoms, each of which has three lone pairs of electrons.

17. (a)
A Lewis structure is shown. A nitrogen atom is single bonded to two hydrogen atoms and a carbon atom. The carbon atom is single bonded to a hydrogen atom and two other carbon atoms. One of these carbon atoms is single bonded to two hydrogen atoms and an oxygen atom. The oxygen atom is bonded to a hydrogen atom. The other carbon is single bonded to two oxygen atoms, one of which is bonded to a hydrogen atom. The oxygen atoms have two lone pairs of electron dots, and the nitrogen atom has one lone pair of electron dots.;

(b)

A Lewis structure is shown. A nitrogen atom is single bonded to two hydrogen atoms and a carbon atom. The carbon atom is single bonded to an oxygen atom and one nitrogen atom. That nitrogen atom is then single bonded to two hydrogen atoms. The oxygen atom has two lone pairs of electron dots, and the nitrogen atoms have one lone pair of electron dots each.;

(c)

A Lewis structure is shown. A carbon atom is single bonded to three hydrogen atoms and a carbon atom. The carbon atom is single bonded to an oxygen atom and a third carbon atom. This carbon is then single bonded to two oxygen atoms, one of which is single bonded to a hydrogen atom. Each oxygen atom has two lone pairs of electron dots.;

(d)

A Lewis hexagonal ring structure is shown. From the top of the ring, three carbon atoms, one nitrogen atom, a carbon atom and a nitrogen atom are single bonded to one another. The top carbon is single bonded to an oxygen, the second and third carbons and the nitrogen atom are each single bonded to a hydrogen atom. The next carbon is single bonded to an oxygen atom and the last nitrogen is single bonded to a hydrogen atom. The oxygen atoms have two lone pairs of electron dots, and the nitrogen atoms have one lone pair of electron dots.;

(e)

A Lewis structure is shown. A carbon atom is single bonded to three oxygen atoms. Two of those oxygen atoms are each single bonded to a hydrogen atom. Each oxygen atom has two lone pairs of electron dots.

19.
A Lewis structure is shown. A carbon atom is single bonded to three hydrogen atoms and another carbon atom. The second carbon atom is double bonded to another carbon atom and single bonded to a hydrogen atom. The last carbon is single bonded to two hydrogen atoms.

21. Each bond includes a sharing of electrons between atoms. 2 electrons are shared in a single bond; four electrons are shared in a double bond; and six electrons are shared in a triple bond.

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